I've also been looking at this agin, and I think the best way is to decide your own 'rules' for the compilation first.
A design strategy if you like.
I've just burned a 2x CD pack for a friend in answer to that eternal "who???" question
It's called just that "John Foxx - Who?" and contains very strictly ONE TRACK from EACH album in chronological order.
Doesn't necessarily 'flow' and could be improved by shuffling the songs about, but that wasn't the object of the exercise.
Includes Ultravox, Nation 12 and a couple of examples of remixxes from a couple of years back. 30 in all.
It was hard to be so disciplined, but I rather fancied myself in that 'Metamatic' minimalist this-is-the model-i-am-using role...